Tannin – classification, analysis and applications

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Journal name: Ancient Science of Life
Original article title: Tannin – classification, analysis and applications
The ANSCI is a peer-reviewed, open-access journal focused on Ayurveda and traditional medicines. It publishes original research, reviews, and literary studies linking traditional knowledge with modern science, covering disciplines like botany, ethnomedicine, pharmacology, and clinical research.
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Original source:

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Author:

K. Ramakrishnan, M. R.V. Krishnan


Ancient Science of Life:

(A quarterly multi-disciplinary scientific research journal in Ayurveda)

Full text available for: Tannin – classification, analysis and applications

Year: 1994

Copyright (license): CC BY-NC-SA


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Summary of article contents:

Introduction

Tannin is a plant-derived chemical constituent recognized since ancient times, playing a significant role in various industries such as leather production and pharmaceuticals. Defining tannin is complex, as it encompasses a diverse group of substances known for their specific physical and chemical properties, particularly their ability to combine with proteins and other polymers. Broadly, tannins are classified into two main types: condensed and hydrolysable tannins, each exhibiting unique characteristics and applications.

Importance of Hydrolysable Tannin

Hydrolysable tannin can be subdivided into two categories: ellagitannin and gallotannin. Ellagitannin is known for its characteristic hexa-hydroxyl diphenyl ester structure and the ability to yield ellagic acid upon hydrolysis. It is sourced from plants such as myrobalans and pomegranate rind. On the other hand, gallotannin, which yields gallic acid upon hydrolysis, is a complex polyphenolic compound commonly found in plant galls. Tannic acid, a prominent type of gallotannin, displays various properties including protein precipitation, gelatin formation, and astringency. These properties make hydrolysable tannins essential not only in leather processing, where they aid in collating protein in hides to create leather but also in traditional medicine formulations for their protein-binding and antimicrobial effects.

Conclusion

The diversity in the nature and composition of tannin across different plant species underscores the need for further research to fully explore its potential applications. Both types of tannin—condensed and hydrolysable—reveal their significance in industries ranging from leather production to pharmaceutical formulations. The understanding of tannin's multifaceted roles can lead to innovative applications, emphasizing its importance in historical and contemporary contexts.

FAQ section (important questions/answers):

What are the two main types of tannins?

Tannins are classified into two main types: condensed tannins and hydrolysable tannins. Condensed tannins are more important but less understood, while hydrolysable tannins can be further divided into ellagitannins and gallotannins.

What role do tannins play in leather processing?

In leather processing, tannins are used to convert animal hides into leather. They work by cross-linking collagen chains in the hide, forming a stable and durable material known as leather.

How are tannins utilized in traditional medicine?

Tannins have been used in Ayurveda, Siddha, and Unani medicine for their properties, such as protein precipitation and antimicrobial effects. They are common ingredients in various formulations to treat ailments like dysentery and strengthen gums.

What are the applications of tannins in other industries?

Tannins find applications across various industries, including ink production, dye manufacturing, water purification, and in the production of adhesives and surface coatings, showcasing their versatility beyond leather and medicinal uses.

Glossary definitions and references:

Scientific and Ayurvedic Glossary list for “Tannin – classification, analysis and applications”. This list explains important keywords that occur in this article and links it to the glossary for a better understanding of that concept in the context of Ayurveda and other topics.

1) Sugar:
Sugar, particularly glucose, is a significant component of hydrolysable tannins, which are esters of sugar and phenolic acids. It contributes to the structural properties of these tannins and is crucial in their chemical reactions during extraction and applications in various industries, including medicine and leather processing.

2) Substance:
Substance refers to the various chemical components present in tannins, which are phenolic compounds derived from plants. These substances can have varying properties and functionalities, including interactions with proteins and polymers, which plays a vital role in their applications across various industries such as leather and medicine.

3) Medicine:
Medicine encompasses the therapeutic applications of tannins, especially in traditional practices such as Ayurveda, Siddha, and Unani. Tannins' ability to precipitate proteins and their antimicrobial properties make them valuable in medicinal formulations and folk remedies, thus highlighting their role in enhancing health and healing.

4) Water:
Water is a crucial solvent in the extraction and application of tannins. Many tannins are water-soluble phenolic compounds, and their effectiveness, especially in the leather industry and medicinal preparations, relies on their solubility, allowing for easier processing and utilization in various aqueous formulations.

5) Honey:
Honey is mentioned as an ingredient in medicinal formulations, particularly in formulations that utilize tannin-rich materials. Its natural antibacterial properties and sweetness enhance the palatability of remedies while also providing additional therapeutic benefits when combined with tannins in Ayurvedic and folk medicine.

6) Purification:
Purification refers to the processes involved in isolating tannins from plant materials, which can include hydrolysis and various chemical treatments. The purification of tannins is essential for analyzing their properties, assessing their functionalities, and ensuring their effectiveness in applications such as medicine, leather, and other industries.

7) Pomegranate:
Pomegranate is a significant source of tannins, particularly ellagitannins. Its rind and other components are historically used in traditional medicine for treating ailments like dysentery. The tannin-rich extracts from pomegranate play a vital role in various formulations in Ayurveda and other medicine systems.

8) Ayurveda (Āyurveda, Ayus-veda):
Ayurveda is a traditional system of medicine from India that utilizes tannin-containing plants in many formulations. Tannins in Ayurveda are valued for their astringent, antibacterial, and healing properties, making them essential ingredients in various remedies, including those for digestive issues and skin treatments.

9) Triphala (Triphalā, Tri-phala):
Triphala is an Ayurvedic formulation consisting of three myrobalans, known for their high tannin content. This combination is touted for its astringent, laxative, and detoxifying properties. It is traditionally used to promote digestion, improve eye health, and as a general health tonic.

10) Science (Scientific):
Science represents the systematic study and analysis of tannins, including their classification, structures, and applications. The ongoing research into tannins, their properties, and their effects in fields like medicine, leather production, and other industries reflects the broader scientific efforts to understand plant-based compounds.

11) Gelatin:
Gelatin is a protein derived from collagen that can react with tannins, leading to precipitation. The ability of tannins to form complexes with proteins like gelatin is significant for applications in the leather industry, where this property aids in the tanning process for creating durable leather.

12) Siddha (Siddhā):
Siddha is a traditional system of medicine practiced mainly in South India, similar to Ayurveda, and incorporates the use of tannins in various formulations. Tannin-based materials in Siddha therapy are known for their health benefits, including antibacterial properties and use in treatments for various ailments.

13) Ashoka (Asoka, Aśoka, Aśokā, Asokā):
Asoka refers to a medicinal plant whose bark is used in traditional formulations that may contain tannins. It is recognized for its therapeutic effects, including haemostatic and astringent properties, making it a valuable component in Ayurvedic medicine, particularly in women's health formulations.

14) Ghi (Ghī, Ghee):
Ghee, a clarified butter, is frequently included in Ayurvedic formulations containing tannins due to its nourishing properties and compatibility with herbs. Ghee enhances the bioavailability of active compounds in medicinal preparations, contributing to the effectiveness of tannin-based remedies in promoting health.

15) Animal hide:
Animal hide is the raw material that undergoes tanning, a process facilitated by the action of tannins. The primary role of tannins is to cross-link collagen fibers in hides, transforming them into leather. This is fundamental in the leather industry, emphasizing the utility of tannins.

16) Antibiotic (Antibacterial):
Antibacterial refers to the property of tannins to inhibit the growth of bacteria, making them valuable in traditional and modern medicinal applications. This property is exploited in Ayurveda and folk medicine to develop remedies that address infections and promote healing in wounds and other ailments.

17) Transformation (Transform, Transforming):
Transforming describes the crucial process through which tannins convert raw animal hides into leather. Tannins chemically alter the structure of collagen fibers in hides, allowing for the creation of durable, rot-resistant leather, which is essential for various applications in the leather industry.

18) Quality:
Quality in this context refers to the effectiveness and characteristics of tannins as they are used in various applications, including leather manufacturing and medicinal formulations. The quality of tannins influences their performance in binding proteins, antimicrobial activity, and overall efficacy in products.

19) Bhasma (Bhasman):
Bhasma refers to a type of Ayurvedic formulation often containing metal ash mixed with plant-derived tannins. These formulations are used in traditional healing practices, and the tannins' properties can enhance the therapeutic effectiveness of Bhasma, promoting healing and overall health.

20) Liquor:
Liquor in this context relates to the aqueous solutions or infusions of tannin obtained from plant materials. These tannin liquors are utilized in leather tanning processes and may also feature in traditional medicine formulations, emphasizing the importance of tannins in various liquid preparations.

21) Dhava (Dhāva):
Dhava refers to a plant species that is known to contain tannins. In traditional medicine, parts of the Dhava plant are used for their health benefits, and its tannin content contributes to its therapeutic properties, reinforcing the importance of plant source materials rich in tannins.

22) Ulcer:
Ulcer refers to a condition where tannins are utilized for their healing properties in traditional medicine. Tannins can help in wound healing due to their ability to precipitate proteins and form protective barriers, making them valuable for treating ulcers and skin injuries.

23) Anna (Aṇṇa, Aññā, Añña, Ānna, Aṉṉa, Aṉṉā):
Anna represents food or nourishment and emphasizes the holistic approach of Ayurveda, where nourishing ingredients rich in tannins are used to enhance health. Tannin-rich formulations may support digestive health and overall wellness, reinforcing the interconnectedness of diet and medicine.

24) Rasa (Rasā, Rasha):
Rasa refers to the taste or essence in Ayurveda, which influences the therapeutic use of various herbal components, including tannins. The astringent properties of tannins may be linked to their taste and their role in traditional recipes and medicinal formulations.

25) Vati (Vāti, Vāṭī, Vatī, Vaṭi):
Vati is a traditional Ayurvedic preparation form, often including powdered herbs mixed with binders. Tannins may be present in these formulations, enhancing medicinal properties and contributing to the effectiveness of the Vati in treating health issues, demonstrating their versatility in Ayurveda.

26) Amla (Amlā, Āmlā):
Amla, or Indian gooseberry, is a fruit rich in vitamin C and tannins, which are valued in traditional medicine for their health benefits. The tannins in Amla contribute to its antioxidant properties, making it a significant ingredient in numerous Ayurvedic formulations for overall health.

27) Shana (Śaṇa, Śana, Sāṇa, Saṇa, Sanā, Sana, Śānā, Saṅa):
Sana, often used in Ayurvedic formulations, may refer to a mixture of healthful ingredients. The inclusion of tannin-rich plant materials in Sana signifies the commitment to harnessing natural properties for therapeutic benefits, reflecting the broader philosophy of wellness in traditional Indian medicine.

28) Salt (Salty):
Salt, although not directly linked to tannins, plays a significant role in traditional medicine where it is often used in combination with herbal remedies. It may enhance the efficacy of tannins and complement their properties in formulations, promoting overall therapeutic effects in various health conditions.

29) Drug:
Drug refers to any substance used for medicinal purposes, where tannins serve as an important component in many herbal medicines. The diverse properties of tannins, including their antimicrobial and astringent effects, make them valuable ingredients in the development and effectiveness of traditional and modern drugs.

Other Science Concepts:

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Discover the significance of concepts within the article: ‘Tannin – classification, analysis and applications’. Further sources in the context of Science might help you critically compare this page with similair documents:

Folk medicine, Triphala Churna, Tannic acid, Chemical constituent, Phenolic compound, Ellagitannin, Condensed tannin, Hydrolysable tannin.

Concepts being referred in other categories, contexts and sources.

Myrobalan.

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